{"id":621,"date":"2023-11-05T21:27:31","date_gmt":"2023-11-05T13:27:31","guid":{"rendered":"http:\/\/172.20.20.103\/?p=621"},"modified":"2023-12-06T08:54:34","modified_gmt":"2023-12-06T00:54:34","slug":"acs-catalysis%e6%8a%a5%e9%81%93%e6%88%91%e6%a0%a1%e5%9f%ba%e4%ba%8e%e8%b6%85%e5%be%ae%e5%ad%94%e7%82%ad%e4%bd%9c%e7%94%a8%e7%9a%84%e5%88%86%e5%ad%90%e6%b0%a7%e5%ae%a4%e6%b8%a9%e6%b4%bb%e5%8c%96","status":"publish","type":"post","link":"http:\/\/172.20.20.103\/?p=621","title":{"rendered":"ACS Catalysis\u62a5\u9053\u6211\u6821\u57fa\u4e8e\u8d85\u5fae\u5b54\u70ad\u4f5c\u7528\u7684\u5206\u5b50\u6c27\u5ba4\u6e29\u6d3b\u5316\u7814\u7a76\u65b0\u8fdb\u5c55"},"content":{"rendered":"\n<p class=\"wp-block-paragraph\">\u8fd1\u65e5\uff0c\u6211\u5ba4\u9f99\u4e1c\u8f89\u6559\u6388\u56e2\u961f\u5728\u8d85\u5fae\u5b54\u70ad\u7ed3\u6784\u7684\u5206\u5b50\u6c27\u5ba4\u6e29\u6d3b\u5316\u673a\u5236\u7684\u7814\u7a76\u4e2d\u53d6\u5f97\u4e86\u6700\u65b0\u8fdb\u5c55\uff0c\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u5728\u50ac\u5316\u9886\u57df\u671f\u520aACS Catalysis (DOI: 10.1021\/acscatal.1c00857)\u4e0a\u3002<\/p>\n\n\n\n<p 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class=\"wp-block-paragraph\">\u6d3b\u6027\u70ad\u662f\u4e00\u7c7b\u5e38\u89c1\u7684\u591a\u5b54\u5438\u9644\u6750\u6599\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u51c0\u5316\u6c34\u8d28\u3001\u5438\u9644\u6709\u673a\u5e9f\u6c14\u3001\u8131\u786b\u8131\u785d\u7b49\u73af\u4fdd\u65b9\u9762\u3002\u672c\u5de5\u4f5c\u901a\u8fc7\u7535\u5b50\u987a\u78c1\u5171\u632f(EPR)\u6280\u672f\u7814\u7a76\u53d1\u73b0\uff0c\u6d3b\u6027\u70ad\u7c7b\u6750\u6599\u80fd\u591f\u5c06\u7a7a\u6c14\u4e2d\u7684\u6c27\u6c14\u5206\u5b50\u5728\u5ba4\u6e29\u4e0b\u76f4\u63a5\u6d3b\u5316\u81f3\u6c27\u81ea\u7531\u57fa(O<sub>2<\/sub>\u2022\u2212)\uff0c\u8fdb\u800c\u5bf9\u6709\u5bb3\u7684\u9178\u6027\u6c14\u4f53\uff08\u5982H<sub>2<\/sub>S\u3001NO\u3001CO\u7b49\uff09\u8fdb\u884c\u50ac\u5316\u6c27\u5316\u3002\u800c\u5176\u4ed6\u7c7b\u7684\u591a\u5b54\u6750\u6599\uff0c\u5982\u5206\u5b50\u7b5b\u3001MOF\u3001COF\u3001ZIF\u7b49\u5747\u65e0\u6cd5\u5b9e\u73b0\u5206\u5b50\u6c27\u7684\u5ba4\u6e29\u6d3b\u5316\uff0c\u4e0d\u5177\u5907\u5ba4\u6e29\u50ac\u5316\u6027\u80fd\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u4e3a\u4e86\u63ed\u793a\u6d3b\u6027\u70ad\u7684\u5ba4\u6e29\u6c27\u6d3b\u5316\u673a\u7406\uff0c\u672c\u5de5\u4f5c\u901a\u8fc7DFT\u7406\u8bba\u8ba1\u7b97\u53d1\u73b0\uff0c\u8d85\u5fae\u5b54\uff08~ 0.4 nm\uff09\u548c\u5177\u6709\u03c0*\u7535\u5b50\u548c\u5bfc\u7535\u6027\u80fd\u7684\u78b3\u5316\u5b66\u7ed3\u6784\u662fO<sub>2<\/sub>\u5206\u5b50\u5ba4\u6e29\u6d3b\u5316\u7684\u5fc5\u8981\u524d\u63d0\u3002\u8fdb\u4e00\u6b65\u7406\u8bba\u8ba1\u7b97\u548c\u5b9e\u9a8c\u9a8c\u8bc1\u8868\u660e\uff0cMgO\u7b49\u91d1\u5c5e\u6c27\u5316\u7269\u80fd\u591f\u5bf9O<sub>2<\/sub>\u2022\u2212\u8fdb\u884c\u6709\u6548\u5bcc\u96c6\uff0c\u8fdb\u800c\u63d0\u9ad8\u6d3b\u6027\u70ad\u4f53\u7cfb\u4e2d\u7684O<sub>2<\/sub>\u2022\u2212\u6d53\u5ea6\uff0c\u63d0\u5347H<sub>2<\/sub>S\u7684\u5ba4\u6e29\u50ac\u5316\u6c27\u5316\u6027\u80fd\u3002\u8fd9\u4e00\u53d1\u73b0\u4e3aO<sub>2<\/sub>\u5206\u5b50\u5ba4\u6e29\u6d3b\u5316\u7684\u5185\u5728\u8d77\u6e90\u63d0\u4f9b\u4e86\u89c1\u89e3\uff0c\u540c\u65f6\u4e5f\u5bf9\u70ad\u57fa\u591a\u5b54\u6750\u6599\u5728\u73af\u5883\u6cbb\u7406\u4e2d\u53d1\u6325\u7684\u4f5c\u7528\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u6211\u6821\u5316\u5de5\u5b66\u9662\u535a\u58eb\u7814\u7a76\u751f\u6f58\u71d5\u51ef\uff0c\u6b64\u6b21\u62a5\u9053\u7684\u662f\u5176\u8fd1\u671f\u53d1\u8868\u7684\u7b2c3\u7bc7\u5173\u4e8e\u6c27\u6d3b\u5316\u548cH<sub>2<\/sub>S\u6c27\u5316\u7684\u7814\u7a76\u6210\u679c\uff08\u524d\u671f\u5de5\u4f5c\u53d1\u8868\u5728Appl Catal B-Environ, 2021, 280, 119444\u3001Appl Catal B-Environ 2020\uff0c262, 118266\u4e0a\uff09\u3002\u901a\u8baf\u4f5c\u8005\u662f\u9f99\u4e1c\u8f89\u6559\u6388\u548c\u5f20\u4e9a\u8fd0\u526f\u7814\u7a76\u5458\u3002\u8be5\u7814\u7a76\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u4ee5\u53ca\u4e2d\u592e\u9ad8\u6821\u57fa\u672c\u79d1\u7814\u4e1a\u52a1\u8d39\u7b49\u9879\u76ee\u7684\u8d44\u52a9\u548c\u652f\u6301\u3002<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u8bba\u6587\u94fe\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acscatal.1c00857\" target=\"_blank\" rel=\"noreferrer noopener\">https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acscatal.1c00857<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u8fd1\u65e5\uff0c\u6211\u5ba4\u9f99\u4e1c\u8f89\u6559\u6388\u56e2\u961f\u5728\u8d85\u5fae\u5b54\u70ad\u7ed3\u6784\u7684\u5206\u5b50\u6c27\u5ba4\u6e29\u6d3b\u5316\u673a\u5236\u7684\u7814\u7a76\u4e2d\u53d6&#46;&#46;&#46;<\/p>\n","protected":false},"author":1,"featured_media":622,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[23],"tags":[],"class_list":["post-621","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-23"],"_links":{"self":[{"href":"http:\/\/172.20.20.103\/index.php?rest_route=\/wp\/v2\/posts\/621","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/172.20.20.103\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/172.20.20.103\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/172.20.20.103\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/172.20.20.103\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=621"}],"version-history":[{"count":1,"href":"http:\/\/172.20.20.103\/index.php?rest_route=\/wp\/v2\/posts\/621\/revisions"}],"predecessor-version":[{"id":623,"href":"http:\/\/172.20.20.103\/index.php?rest_route=\/wp\/v2\/posts\/621\/revisions\/623"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/172.20.20.103\/index.php?rest_route=\/wp\/v2\/media\/622"}],"wp:attachment":[{"href":"http:\/\/172.20.20.103\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=621"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/172.20.20.103\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=621"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/172.20.20.103\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=621"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}